Some plants and animals have chemicals which can send out light, when they get energy delivered to them. So instead of the energy packets making a muscle move, they deliver it to the light emitting molecule
Fireflies glow because of a chemical reaction called “bioluminescence”. There are specialised organs found in fireflies, and in these organs, a special enzyme called “luciferase” catalyses a reaction to produce light. They use this mainly for selecting a mate, and there are other organisms that do this too.
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